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Beilstein J. Org. Chem. 2015, 11, 1226–1234, doi:10.3762/bjoc.11.136
Graphical Abstract
Scheme 1: Preparation of the chloroamides.
Scheme 2: First experiments for the intermolecular radical addition.
Scheme 3: Reaction of sterically hindered N-chlorosulfonamides.
Scheme 4: Proposed mechanism of the chlorination.
Scheme 5: Ring opening in the case of cationic or radical intermediates.
Scheme 6: Addition to unsaturated alcohols prone to halocyclization.